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Luminescent Metal Complexes

G. Accorsi, N. Armaroli, A. Barbieri, F. Barigelletti, M. Cocchi, V. Fattori, L. Flamigni, Y. Rio, C. Sabatini, B. Ventura, D. Virgili, Y. Zheng

Ru(bpy)3 complex The design, synthesis, and characterization of luminescent metal complexes is a topic of widespread interest that finds applications in many different areas of chemical research from supramolecular to solid-state chemistry. Such complexes have been employed, for instance, in: (i) energy conversion systems, as dye-sensitized solar cells and electroluminescent devices (OLEDs); (ii) catalysis; (iii) probes for drug or cellular systems; (iv) temperature and pressure sensors. The rational design of ligands is a crucial step toward the synthesis of photo- and redox-active building blocks that can be used as components of more complex multifunctional systems. Much of our effort focuses on the study of electronic excited states of transition metal complexes, especially late transition metal complexes.

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